Improved line parameters for the ν_{3} and ν_{2} + ν_{3}  ν_{2} bands of ^{14}N ^{16}O _{2}
Abstract
A Hamiltonian taking explicity into account Coriolis interactions is used to reproduce the rotational energy levels of the interacting states {(020), (100), (101)} and {(030), (011)} of NO _{2}. The vibrationrotation levels calculated in this way are then used together with the best available spinrotation constants of the (000), (010), (001), and (011) vibrational states and with the recent determination of the dipole moment derivative {∂μ _{z}}/{∂q _{3}} = 0.4182 ± 0.0085D to compute an improved set of line parameters (positions and intensities) for the ν_{3} and ν_{2} + ν_{3}  ν_{2} bands of ^{14}N ^{16}O _{2} absorbing in the 6.2μm region.
 Publication:

Journal of Molecular Spectroscopy
 Pub Date:
 September 1982
 DOI:
 10.1016/00222852(82)902399
 Bibcode:
 1982JMoSp..95...72C