Method of the effective flexible gyroscope in polyatomic molecules
Abstract
On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the “effective” rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.
- Publication:
-
Soviet Physics Journal
- Pub Date:
- August 1975
- DOI:
- 10.1007/BF01110030
- Bibcode:
- 1975SvPhJ..18.1106M