Possible structural origin of superconductivity in Sr-doped B i2S e3
Abstract
Doping bismuth selenide (B i2S e3 ) with elements such as copper and strontium (Sr) can induce superconductivity, making the doped materials interesting candidates to explore potential topological superconducting behaviors. It was thought that the superconductivity of doped B i2S e3 was induced by dopant atoms intercalated in van der Waals gaps. However, several experiments have shown that the intercalation of dopant atoms may not necessarily make doped B i2S e3 superconducting. Thus, the structural origin of superconductivity in doped B i2S e3 remains an open question. Herein, we combined material synthesis and characterization, high-resolution transmission electron microscopy, and first-principles calculations to study the doping structure of Sr-doped B i2S e3 . We found that the emergence of superconductivity is strongly related with n -type dopant atoms. Atomic-level energy-dispersive x-ray mapping revealed various n -type Sr dopants that occupy intercalated and interstitial positions. First-principles calculations showed that the formation energy of a specific interstitial Sr doping position depends strongly on the Sr doping level. This site changes from a metastable position at low Sr doping level to a stable position at high Sr doping level. The calculation results explain why quenching is necessary to obtain superconducting samples when the Sr doping level is low and also why slow furnace cooling can yield superconducting samples when the Sr doping level is high. Our findings suggest that Sr atoms doped at interstitial locations, instead of those intercalated in van der Waals gaps, are most likely to be responsible for the emergence of superconductivity in Sr-doped B i2S e3 .
- Publication:
-
Physical Review Materials
- Pub Date:
- January 2018
- DOI:
- 10.1103/PhysRevMaterials.2.014201
- arXiv:
- arXiv:1803.02947
- Bibcode:
- 2018PhRvM...2a4201L
- Keywords:
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- Condensed Matter - Superconductivity
- E-Print:
- 21 pages, 4 figures