Biomarker signature of Greenland sediments: from modern rivers and soils to MIS 5e and 11 records

Better constraining the evolution of the Greenland Ice Sheet (GrIS) is crucial for a broader understanding of past and future climate changes. Previous studies reported that the GrIS was significantly smaller during interglacial periods MIS 5e and MIS 11 than at present [1,2], which suggests that a bigger fraction of Greenland was covered by vegetation and soils. To investigate whether terrestrial biomarkers provide new constraints on the dynamics of the GrIS over the past interglacials, we characterised the biomarker composition (GDGTs and n-alkanes), as well as the bulk geochemistry (TOC, δ13C, C-14), of modern sediments from southwestern Greenland and of Eirik Drift core IODP-303-U1305 over MIS5e and 11. Rivers in southwestern Greenland constitute the main link between the Greenland Ice Sheet (GrIS) and the ocean. Understanding the composition of suspended river sediments gives insights into the source of organic carbon that is mobilised and further exported to the ocean. To address these questions, biomarkers in suspended sediments and soils coming from Kangerlussuaq, southwestern Greenland, were measured. Kangerlussuaq is located in the most sensitive region of Greenland with regard to climate change, and is a good analogue for interglacials. Preliminary results (e.g. biomarker concentrations, MAT, CPI, ACL) show that soils or lakes are not the only source of organic matter in these rivers, and suggest that part of the biomarker signature is inherited from older, presently subglacial, organic pools. The Eirik Drift accumulates material that is eroded from the eastern and southern Greenland margin, and it has been shown to record significant environmental changes of the GrIS over MIS 5e and MIS 11 [1,2,3]. However, the GDGT and n-alkane characterisation of drift sediments from IODP-303-U1305 do not show a significant response of the biomarker record to these interglacials. [1] Colville, E. J., et al., 2011 - Science 333, 620-623. [2] Reyes, A. V., et al., 2014 - Nature 510, 525-528. [3] de Vernal, A., & Hillaire-Marcel, C., 2008 - Science, 320 (5883), 1622-1625.