Ion exhange and molecular sorption of oxalic acid with a highly basic anion exchanger
Abstract
Ab initio modeling of a matrix fragment of resin and geometry optimization of the molecular structure of oxalic acid were performed. The isotherm of oxalic acid sorption with AV-17-8 anion exchange resin was obtained by the variable concentrations technique. The ion-exchange and molecular components of sorbate fixation with the ion exchanger were determined. The hydration of the highly basic anion exchanger that absorbed different quantities of dicarboxylic acid was evaluated by the centrifuging method. The dependence of the amount of water and sorbate concentration in the resin was linear antibatic.
- Publication:
-
Russian Journal of Physical Chemistry A
- Pub Date:
- April 2014
- DOI:
- 10.1134/S003602441404013X
- Bibcode:
- 2014RJPCA..88..697K
- Keywords:
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- highly basic anion exchange resin;
- oxalic acid;
- ion exchange;
- molecular sorption