Contribution of thermoelectric and electrochemical effects to spontaneous potential signals induced by water injection into hydrocarbon reservoirs
Abstract
Recent work has demonstrated that downhole measurements of streaming potential, using electrodes mounted on the outside of insulated casing, may be used to inform production strategies in oil and gas reservoirs. However, spontaneous potentials due to thermoelectric and/or electrochemical effects may also be present during production and may contribute to the signal measured at the production well. We present a workflow to numerically model spontaneous potentials in the subsurface and ascertain their magnitude in oil reservoirs during production. Our results suggest that the injection of seawater, which typically has a different temperature and salinity to the formation brine, leads to the generation of both thermoelectric and electrochemical potential signals which may be measured at the production well. We observe a peak in the thermoelectric potential before and after the temperature front, with a change in sign occurring close to the midpoint of the front, and the signal decaying with distance from the front. The electrochemical potential has a similar profile, with a change in sign occurring close to the location of the salinity front. In both cases, the absolute magnitude of the signal is related to the overall temperature and/or salinity contrast between the injected fluids and the formation brine, and the magnitude of the thermoelectric or electrochemical coupling coefficient. The lag in the temperature front relative to the saturation front leads to a negligible thermoelectric potential signal at the production well until long after water breakthrough occurs. In contrast, the electrochemical potential contributes significantly to the spontaneous potential measured at the production well before the waterfront arrives, as the salinity front and the saturation front coincide. However, the dependency of the thermoelectric and electrochemical coupling coefficients upon temperature and/or salinity is still uncertain, especially at partial water saturation. We have used the maximum theoretical limit, in the case of the perfect membrane, to estimate these parameters. These results imply that measurements of the spontaneous potential at a production well will combine contributions from both streaming and electrochemical effects, and may be used to detect an advancing waterfront some time before water breakthrough occurs at the well. Moreover, inversion of the measured signals could be used to determine the water saturation in the vicinity of the well, and to regulate flow into the well using control valves in order to maintain or increase oil production.
- Publication:
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AGU Fall Meeting Abstracts
- Pub Date:
- December 2009
- Bibcode:
- 2009AGUFMNS31A1150G
- Keywords:
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- 0545 COMPUTATIONAL GEOPHYSICS / Modeling;
- 0915 EXPLORATION GEOPHYSICS / Downhole methods;
- 3653 MINERALOGY AND PETROLOGY / Fluid flow;
- 5109 PHYSICAL PROPERTIES OF ROCKS / Magnetic and electrical properties