Chemostratigraphy and trace element pattern of authigenic pyrite in a Frasnian-Fammenian transition section (Büdesheimer bach, Germany)
Abstract
Trace element contents in authigenic pyrite were investigated in relationship to the geochemistry of host rocks in a 160 m deep drilling at Büdesheimer Bach (Prümer Mulde, Germany), in order to put constrains on possible changes in depositional conditions and seawater composition related to the Kellwasser events (Frasnian/Fammenian transition). The approach is based on the observation that the trace element pattern of authigenic pyrite is controlled by genetic conditions (Stüben et al., 2002) and that the content of elements with generally high degree of pyritization (DTMP, degree of trace metal pyritization, like As, Mo, Co, Ni, etc.) depends on their availability at the site of pyrite formation (e.g. Huerta-Diaz and Morse, 1992). The distribution of trace elements in the bulk rock essentially reflects mineralogical composition and redox conditions which are mainly controlled by the flux of organic matter entering the sediment. The lower and upper Kellwasser horizons are marked by an increase in carbonate and organic carbon content (up to 2%), coupled with an increase in the degree of pyritization of Fe (DOP: 0.4-0.8), indicating a change from normal marine to suboxic/anoxic conditions. A simultaneous drop in the Ba content of the host lithology, which usually is used as a proxy for paleoproductivity, can be explained by the removal of Ba dissolved in pore water under anoxic conditions (McManus et al., 1998). While low in the host rock, the Ba content of authigenic pyrite is high in these horizons, suggesting that pyrite may preserve the initial composition of pore water even for some elements with generally low DTMP, like Ba. Consequently, Ba content in pyrite may serve as indicator for productivity even when the Ba content of sediment can not be used due to its poor preservation. During these anoxic episodes also a significant increase in the content of As, U, V was registered in pyrite. Opposite to these, others like Ni, Co, Ag show a decrease in their concentrations. In using the trace element pattern of pyrite for paleoreconstruction care must be taken to a priori discriminate (e.g., based on grain morphology) among different genetical types which could be present in the same sample (syngenetic, diagenetic, epigenetic, pyritized fossil fragments, etc.). Huerta-Diaz and Morse, 1992: Geochim. Cosmochim. Acta 56, 2681-2702; Stueben et al., 2002: EOS Trans. AGU, 83(47), Fall Meet. Suppl., Abstract PP51A-0267; McManus et al., 1998, Geochim. Cosmochim. Acta 62, 3453-3473.
- Publication:
-
EGS - AGU - EUG Joint Assembly
- Pub Date:
- April 2003
- Bibcode:
- 2003EAEJA.....3570P