HF infrared emission from the reaction of atomic fluorine with 2,2‧-azobisisobutane, azodicarbonic acid dimethyl ester and t-butylisonitrile
Abstract
In the reactive systems F + N 2( t-C 4H 9) 2, F + N 2(COOCH 3) 2 and F + t-C 4H 9NC, infrared emission spectra were recorded from HF in the fundamental region under relaxation-free conditions. The primary vibrational and rotational distributions were obtained. The vibrational distributions are for F + N 2(C 4H 9): N1: N2: N3=0.46:0.49:0.05; for F + N 2(COOCH 3) 2: N1: N2: N3=0.43:0.47:0.10; for F + t-C 4H 9NC: N1: N2: N3=0.46:0.51:0.03.
- Publication:
-
Chemical Physics Letters
- Pub Date:
- June 1990
- DOI:
- 10.1016/0009-2614(90)85656-W
- Bibcode:
- 1990CPL...169..603D