Preparation and properties of single crystals of hydrogen bis(phthalocyaninato) neodymium(3)
Abstract
Partially oxidized metallomacrocycles yield low-dimensional conducting materials. For example, NiPcI (Pc = phthalocyanine) crystallizes with the formation of stacked, planar NiPc units and exhibits metal-like conductivity parallel to the stacking direction. Lanthanide elements form sandwich-type compounds with phthalocyanine. In this paper, we report the electrochemical synthesis, electrical conductivity, and magnetic behavior of single crystals of bis(c)Nd(III).
- Publication:
-
Unknown
- Pub Date:
- August 1984
- Bibcode:
- 1984ppsc.rept.....S
- Keywords:
-
- Electrical Resistivity;
- Electrochemistry;
- Hydrogen Compounds;
- Magnetic Properties;
- Neodymium Compounds;
- Semiconductors (Materials);
- Single Crystals;
- Synthesis (Chemistry);
- Phthalocyanin;
- Preparation;
- Sandwich Structures;
- Stacks;
- Solid-State Physics