Fine-structure transitions of the carbon isoelectronic sequence C, N+, and O2 + induced by collisions with atomic hydrogen

Fine-structure transitions can be involved in various processes including photon absorption, charge transfer, and inelastic collisions between ions, electrons, and neutral atoms. We present fine-structure excitation and relaxation cross-sections for the collisions of the first few members of the carbon isoelectronic sequence (C, N⁺ and O^{2 +}) with atomic hydrogen calculated using quantum-mechanical methods. For C, the scattering theory and computational approach is verified by comparison with previous calculations. The rate coefficients for the collisional processes are obtained. For N⁺ and O^{2 +}, the transitions correspond to the lines [O III] 52 μm, [O III] 88 μm, [N II] 122 μm, and [N II] 205 μm, observed in the far-infrared in the local universe and more recently in high-redshift galaxies using radio interferometry. The influence of different potentials on the cross-sections and rate coefficients are demonstrated.