A unified, geometric framework for nonequilibrium protocol optimization
Abstract
Controlling thermodynamic cycles to minimize the dissipated heat is a longstanding goal in thermodynamics, and more recently, a central challenge in stochastic thermodynamics for nanoscale systems. Here, we introduce a theoretical and computational framework for optimizing nonequilibrium control protocols that can transform a system between two distributions in a minimally dissipative fashion. These protocols optimally transport a system along paths through the space of probability distributions that minimize the dissipative cost of a transformation. Furthermore, we show that the thermodynamic metric -- determined via a linear response approach -- can be directly derived from the same objective function that is optimized in the optimal transport problem, thus providing a unified perspective on thermodynamic geometries. We investigate this unified geometric framework in two model systems and observe that our procedure for optimizing control protocols is robust beyond linear response.
- Publication:
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arXiv e-prints
- Pub Date:
- May 2022
- DOI:
- 10.48550/arXiv.2205.01205
- arXiv:
- arXiv:2205.01205
- Bibcode:
- 2022arXiv220501205C
- Keywords:
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- Condensed Matter - Statistical Mechanics