Chemometric approach to evaluate the chemical behavior of rainwater at high altitude in Shaune Garang catchment, Western Himalaya

The present research has been performed to analyze the chemical behavior of rainwater of the Shaune Garang catchment (32.19° N, 78.20° E) in the Baspa basin, located at a high elevation (4221 m above mean sea level) in the Himachal Himalaya, India. During the study period, sixteen rainwater samples were collected from the Shaune Garang catchment at five different sites. The volume-weighted mean (VWM) pH value of rainwater ranged between 4.59 and 6.73, with an average value of 5.47 ± 0.69, indicating the alkaline nature of rainfall. The total ionic strength in the rainwater ranged from 113.4 to 263.3 µeq/l with an average value of 169.1 ± 40.4 µeq/l. The major dominant cations were Ca²⁺ (43.10%) and Na⁺ (31.97%) and anions were Cl⁻ (37.68%), SO₄²⁻ (28.71%) and NO₃⁻ (23.85%) in rainwater. The ionic ratios were calculated among all the ions. The fraction of (NO₃⁻ +Cl⁻) with SO₄²⁻ was measured as 2.3, which specifies sour faces of rainwater due to HNO₃, H₂SO₄, and HCl. A multivariate statistical assessment of rainwater chemistry through Principal Component Analysis (PCA) shows the significance of four factors controlling 78.37% of the total variance, including four-component (PC1 explained 27.89%, PC2 explained 24.98%, PC3 explained 14.64%, PC4 explained 10.85%). However, the individual contribution of Factor 1(PC1) explains 27.89% of the total variance (78.37%) and displays a strong optimistic loading for Ca²⁺ and Cl⁻. Further, high loading of Ca²⁺ and NO₃⁻ and moderate loading of SO₄²⁻ signify the contribution of burning fossil fuel and soil dust. Anthropogenic and natural pollutants influence the composition of rainwater in the pristine Himalayas due to local and long-distance transportation. The study area receives precipitation from the West and North-West, transporting dust and fossil fuel emissions from the Thar Desert and Northwestern countries.