Stretchable slide-ring supramolecular hydrogel for flexible electronic devices

Slide-ring materials with movable cross-links have received attention due to their excellent mechanical properties. However, due to the poor solubility of polyrotaxane and low synthesis efficiency, their applications are hindered. Here, we use hydroxypropyl-modified α-cyclodextrin (Hy-α-CD) and Acrylamide-PEG₂₀₀₀₀-Acrylamide (ACA-PEG₂₀₀₀₀-ACA) to construct a polypseudorotaxane with good water solubility. Through photo-initiated polymerization of polypseudorotaxane with acrylamide in-situ, the capped polyrotaxane was easily obtained and further cross-linked by 1,4-butanediol diglycidyl ether in sodium hydroxide solution to form a slide-ring supramolecular hydrogel. The hydrogel can be stretched to 25.4 times its original length, which recovers rapidly on unloading, and the addition of Ca²⁺ ions during crosslinking enhances ionic conductivity. The Ca²⁺-doped hydrogels are used to prepare wearable strain sensors for monitoring human motion.