Simulating quantum chemistry in the restricted HartreeFock space on a qubitbased quantum computing device
Abstract
Accurate quantum chemistry simulations remain challenging on classical computers for problems of industrially relevant sizes and there is reason for hope that quantum computing may help push the boundaries of what is technically feasible. While variational quantum eigensolver (VQE) algorithms may already turn noisy intermediate scale quantum (NISQ) devices into useful machines, one has to make all efforts to use the scarce quantum resources as efficiently as possible. We combine the socalled restricted approximation from computational quantum chemistry with techniques for simulating molecular chemistry on gatebased quantum computers and thereby obtain a much more resource efficient algorithm with little accuracy loss. In fact, we show that using the quantum resources freed up by means of the restricted approximation for increasing the basis set can lead to more accurate results and reductions in the necessary number of quantum computing runs (shots) by several orders of magnitude, already for a simple system such as lithium hydride.
 Publication:

arXiv eprints
 Pub Date:
 January 2020
 arXiv:
 arXiv:2002.00035
 Bibcode:
 2020arXiv200200035E
 Keywords:

 Quantum Physics
 EPrint:
 9 pages, 4 figures