Shape-Anisotropy-Induced Ordered Packings in Cylindrical Confinement

Densest possible packings of identical spheroids in cylindrical confinement have been obtained through Monte Carlo simulations. By varying the shape anisotropy of spheroids and also the cylinder-to-spheroid size ratio, a variety of densest possible crystalline structures have been discovered, including achiral structures with specific orientations of particles and chiral helical structures with rotating orientations of particles. Our findings reveal a transition between confinement-induced chiral ordering and shape-anisotropy-induced orientational ordering and would serve as a guide for the fabrication of crystalline wires using anisotropic particles.