The Great Oxidation Event preceded a Paleoproterozoic "snowball Earth"

The causality between the Paleoproterozic Great Oxidation Event (GOE) and a global "snowball Earth" glaciation has remained unresolved due to an inability to determine their relative timing. We present quadruple sulfur isotope data from northwest Russia which constrain the GOE between 2,501 and 2,434 Ma. These are the tightest temporal and stratigraphic constraints ever presented for the GOE and show that the GOE predates Paleoproterozic glaciation in Russia and snowball Earth deposits in South Africa. Our results preclude hypotheses of Earth's oxygenation in which global glaciation precedes or causes the evolution of oxygenic photosynthesis.