Synthesis, structure, Hirshfeld surface analysis and photophysical studies of red emitting europium acetylacetonate complex incorporating a phenanthroline derivative
Abstract
Red emitting [Ln(acac)3(Br2-phen)] [Ln: Sm(III) and Eu(III)] complexes were synthesized. Short contacts and their contribution in crystal packing were analyzed. Detailed photophysical properties of complexes were analyzed. Eu(III) complex showed large stimulated emission cross-section (σ(0→2) = 1.27 × 10‑20 cm2).
- Publication:
-
Journal of Photochemistry and Photobiology A: Chemistry
- Pub Date:
- May 2019
- DOI:
- Bibcode:
- 2019JPPA..377..268I
- Keywords:
-
- Lanthanide;
- β-Diketone;
- Hirshfeld surface analysis;
- Laser properties