Laboratory spectroscopic study of the 15N isotopomers of cyanamide, H2NCN, and a search for them toward IRAS 16293-2422 B

Context. Cyanamide is one of the few interstellar molecules containing two chemically different N atoms. It was detected recently toward the solar-type protostar IRAS 16293-2422 B together with H₂N¹³CN and HDNCN in the course of the Atacama Large Millimeter/submillimeter Array (ALMA) Protostellar Interferometric Line Survey (PILS). The detection of the ¹⁵N isotopomers or the determination of upper limits to their column densities was hampered by the lack of accurate laboratory data at the frequencies of the survey.
Aims: We wanted to determine spectroscopic parameters of the ¹⁵N isotopomers of cyanamide that are accurate enough for predictions well into the submillimeter region and to search for them in the PILS data.
Methods: We investigated the laboratory rotational spectra of H₂¹⁵NCN and H₂NC¹⁵N in the selected region between 192 and 507 GHz employing a cyanamide sample in natural isotopic composition. Additionally, we recorded transitions of H₂N¹³CN.
Results: We obtained new or improved spectroscopic parameters for the three isotopic species. Neither of the ¹⁵N isotopomers of cyanamide were detected unambiguously in the PILS data. Two relatively clean lines can be tentatively assigned to H₂¹⁵NCN. If confirmed, their column densities would imply a low ¹⁴N/¹⁵N ratio for cyanamide toward this source.
Conclusions: The resulting line lists should be accurate enough for observations up to about 1 THz. More sensitive observations, potentially at different frequencies, may eventually lead to the astronomical detection of these isotopic species.

Transition frequencies for each isotopic species are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/623/A93