Surfactant-controlled ink drying enables high-speed deposition of perovskite films for efficient photovoltaic modules
Abstract
Novel photovoltaic technologies such as perovskites hold the promise of a reduced levelized cost of electricity, but the low-cost potential depends on the ability to scale-up solution-based deposition. So far, complex fluid dynamics have limited the solution deposition of uniform pinhole-free organic-inorganic perovskite thin films over large areas. Here, we show that very small amounts (tens of parts per million) of surfactants (for example, uc(l)-α-Phosphatidylcholine) dramatically alter the fluid drying dynamics and increase the adhesion of the perovskite ink to the underlying non-wetting charge transport layer. The additives enable blading of smooth perovskite films at a coating rate of 180 m h-1 with root-mean-square roughness of 14.5 nm over 1 cm. The surfactants also passivate charge traps, resulting in efficiencies over 20% for small-area solar cells. Fast blading in air of perovskite films results in stabilized module efficiencies of 15.3% and 14.6% measured at aperture areas of 33.0 cm2 and 57.2 cm2, respectively.
- Publication:
-
Nature Energy
- Pub Date:
- May 2018
- DOI:
- 10.1038/s41560-018-0153-9
- Bibcode:
- 2018NatEn...3..560D