Chemical state analysis of Cl Kα and Kβ1,3 X-ray emission lines using polychromatic WDXRF spectrometer

With the support of research projects focusing on sampling and data analysing of different varieties of chemical compounds, wavelength dispersive X-ray fluorescence (WDXRF) technique is commonly used in many research laboratories throughout the world wide to determine the elemental composition of various unknown samples. In the present study, first time we have employed polychromatic S8 TIGER WDXRF spectrometer to study the chemical state analysis in Cl Kα and Kβ_1,3 X-ray emission lines. A Voigt function is used to determine the central peak position of the K shell emission lines in all samples. From the present measurements, it is seen that both positive and negative shifts have been observed in Cl Kα (2.622 keV) and Kβ_1,3 (2.817 keV) emission peaks. It has been also seen that the effective charge, relative line-width and relative intensity ratio I(Kβ_1,3/Kα) are found proportional with the chemical shift. Furthermore, a parabolic relation is also established between them.