Structural relaxations in the bulk amorphous alloy Fe61Co10Ti3Y6B20

The paper presents studies of annealing effect on the disaccommodation phenomenon in bulk amorphous alloy Fe₆₁Co₁₀Ti₃Y₆B₂₀. The investigated sample was prepared by suction-casting method in the form of rod. The annealing process has been performed at temperature well below the crystallisation temperature. The amorphous structure has been confirmed using X-ray diffractometer. The susceptibility and its disaccommodation were determined using completely automated set up. The disaccommodation curve was decomposed into three elementary processes, each of them was described by Gaussian distribution of relaxation times. The obtained results indicate that the disaccommodation phenomenon in studied alloy is related with directional ordering of atom pairs near the free volumes; this is in agreement with H. Kronmüller's theorem.