Source of the Organic Matter and Land-Marine Interaction Phases in Great Rann of Kachch Basin, India

Using δ13C and C/N ratio of sedimentary organic matter (OM) in 14C AMS dated sediment core from central Great Rann of Kachchh (GRK) basin, we track sediment dispositional history since 18 ka BP. Temporal changes in the δ13C and C/N ratios were inferred in terms of OM source, which could be function of river discharge, relative sea level changes, and also due to land-cover changes in the catchment area. The down core variations in TOC vs TC doesn't show significant correlation suggesting diverse origin of the OM in GRK sediments. Between 18-13 ka BP, pulses of high C/N ratio (18-34) and depleted δ13C (average -23‰; with respect to typical marine -21‰) values hint terrestrially derived OM in rather overall marine environment. High terrestrial OM input from riverine inputs in post glacial period could be relatable to intense monsoonal conditions. Later to this phase, between 14-10 ka BP, C/N ratios show large fluctuations indicating rapidly fluctuating environment, albeit δ13C remains relatively stable at -21‰ typical of marine OM. A significant positive incursion in C/N ratio (45-60) is seen during early-mid Holocene time ( 10-6 ka BP) with and highly depleted δ13C ( -25‰) values indicating enhanced terrestrial OM input. This could be owing to increased riverine fluxes to the basin under intensified monsoonal climate. Between 6-2.5 ka BP during mid-Holocene, C/N ratios shows declining trend with enriched δ13C values, suggesting presence of marine OM source at the core-site. This overlaps with the weaker monsoonal conditions prevailing in the northwest India. Lake records from Rajasthan also support this contention. After 2.5 ka BP, C/N ratios indicate marine OM values, whereas δ13C fluctuates from marine to terrestrial values indicating `mixed-source' of the OM during this period, most likely due to unstable land-marine conditions and large-scale reworking of sediments.