Size distribution of ring polymers
Abstract
We present an exact solution for the distribution of sample averaged monomer to monomer distance of ring polymers. For non-interacting and local-interaction models these distributions correspond to the distribution of the area under the reflected Bessel bridge and the Bessel excursion respectively, and are shown to be identical in dimension d ≥ 2, albeit with pronounced finite size effects at the critical dimension, d = 2. A symmetry of the problem reveals that dimension d and 4 - d are equivalent, thus the celebrated Airy distribution describing the areal distribution of the d = 1 Brownian excursion describes also a polymer in three dimensions. For a self-avoiding polymer in dimension d we find numerically that the fluctuations of the scaled averaged distance are nearly identical in dimension d = 2, 3 and are well described to a first approximation by the non-interacting excursion model in dimension 5.
- Publication:
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Scientific Reports
- Pub Date:
- June 2016
- DOI:
- 10.1038/srep27661
- arXiv:
- arXiv:1501.06151
- Bibcode:
- 2016NatSR...627661M
- Keywords:
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- Condensed Matter - Soft Condensed Matter;
- Condensed Matter - Statistical Mechanics;
- Physics - Data Analysis;
- Statistics and Probability
- E-Print:
- Supplementary Material added at the end of text