Importance of the completeness of the configuration interaction and close coupling expansions in R-matrix calculations for highly charged ions: electron-impact excitation of Fe20+
Abstract
We have carried out two intermediate coupling frame transformation (ICFT) R-matrix calculations for the electron-impact excitation of {{C}}-like {{Fe}}20+, both of which use the same expansions for their configuration interaction (CI) and close-coupling (CC) representations. The first expansion arises from the configurations 2{{{s}}}2 2{{{p}}}2,2{{s}} 2{{{p}}}3,2{{{p}}}4, \{2{{{s}}}2 2{{p}},2{{s}} 2{{{p}}}2,2{{{p}}}3\} {nl}, with n = 3, 4, for l=0-3, which give rise to 564 CI/CC levels. The second adds configurations 2{{{s}}}2 2{{p}} 5{{l}}, for l=0-2, which give rise to 590 CI/CC levels in total. Comparison of oscillator strengths and effective collision strengths from these two calculations demonstrates the lack of convergence in data for n = 4 from the smaller one. Comparison of results for the 564 CI/CC level calculation with an earlier ICFT R-matrix calculation which used the exact same CI expansion but truncated the CC expansion to only 200 levels demonstrates the lack of convergence of the earlier data, particularly for n = 3 levels. Also, we find that the results of our 590 CC R-matrix calculation are significantly and systematically larger than those of an earlier comparable DW-plus-resonances calculation. Thus, it is important still to take note of the (lack of) convergence in both atomic structural and collisional data, even in such a highly charged ion as Fe20+, and to treat resonances non-perturbatively. This is of particular importance for Fe ions given their importance in the spectroscopic diagnostic modelling of astrophysical plasmas.
- Publication:
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Journal of Physics B Atomic Molecular Physics
- Pub Date:
- April 2016
- DOI:
- Bibcode:
- 2016JPhB...49h5203F