Coupling Stable Water Isotopes in Vapor and Precipitation to Raindrop Size Distributions at a Mid-latitude Tall-tower Site to Evaluate the Role of Rain Evaporation in Boundary Layer Moisture Recycling

The continental boundary layer moisture balance plays an important role in regulating water and energy exchange between the surface and the atmosphere, yet the mechanisms associated with moistening and drying are both poorly observed and modeled. Stable water isotope ratio measurements can provide insights into air mass origins, convection dynamics and mechanisms dominating atmosphere-land surface water fluxes. Profiles can be exploited to improve estimates of boundary layer moistening associated with evaporation of falling precipitation and contributions from surface evapotranspiration. We present two years of in situ tower-based measurements of isotope ratios of water vapor and precipitation (δD and δ18O) and raindrop size distributions from the Boulder Atmospheric Observatory (BAO) tall-tower site in Erie, Colorado. Isotope vapor measurements were made at 1 Hz with a full cycle from the surface to 300 meters recorded every 80 minutes. At the surface and 300m, water samples were collected during precipitation events and raindrop sizes were measured continuously using Parsivel instruments. We use this unique suite of measurements and, in particular, exploit the differences between the surface and 300m observations to constrain the surface layer hydrological mass balance during and after rain events, and evaluate parameterization choices for rain evaporation and moisture recycling in current isotope-enabled climate models. Aggregate raindrop size measurements showed shifts from populations of smaller raindrops at 300m to larger raindrops at the surface, contrary to what is expected for rain evaporation. Convective storms resulted in more uniform signatures between the surface and 300m, as well as longer isotope equilibration and adjustment time scales, whereas low Dexcess signatures (<9 to negative) during stratiform drizzle events were indicative of a greater degree of rain evaporation. Our observational results suggest that water vapor-rain equilibration is rarely achieved, and modification of the kinetic fractionation factor is necessary to better capture drop-size related isotope changes. This has implications not only for refining current global climate models, but also for interpreting proxy records connected to rainfall signatures that aid in understanding past hydrology.