Authigenic Carbonate Fans from Lower Jurassic Marine Shales (Alberta, Canada)
Abstract
Authigenic aragonite seafloor fans are a common occurrence in Archean and Paleoproterozoic carbonates, as well as Neoproterozoic cap carbonates. Similar carbonate fans are rare in Phanerozoic strata, with the exception of two mass extinction events; during the Permo-Triassic and Triassic-Jurassic boundaries, carbonate fans formed at the sediment-water interface and within the sediment, respectively. These crystal fans have been linked to carbon cycle perturbations at the end of the Permian and Triassic periods driven by rapid flood volcanism. The Early Jurassic Toarcian Ocean Anoxic Event (T-OAE) is also correlated with the emplacement of a large igneous province, but biological consequences were more modest. We have identified broadly comparable fibrous calcite layers (2-10 cm thick) in Pliensbachian-Toarcian cores from Alberta, Canada. This work focuses on the geochemical and petrographic description of these fans and surrounding sediment in the context of the T-OAE. At the macroscale, carbonates exhibit a fan-like (occasionally cone-in-cone) structure and displace the sediment around them as they grew. At the microscale, the carbonate crystals (pseudomorphs of aragonite) often initiate on condensed horizons or shells. Although they grow in multiple directions (growth within the sediment), the predominant crystal growth direction is towards the sediment-water interface. Resedimentation of broken fans is evidence that crystal growth was penecontemporaneous with sedimentation. The carbon isotope composition of the fans (transects up bladed crystals) and elemental abundances within the layers support shallow subsurface, microbially mediated growth. The resemblance of these Early Jurassic fibrous calcite layers to those found at the end-Triassic and their paucity in the Phanerozoic record suggest that analogous processes occurred at both events. Nevertheless, the Pliensbachian-Toarcian carbonate fans occur at multiple horizons and while some are within the T-OAE, others are significantly above and below the event. The formation of these authigenic layers cannot be driven exclusively by the geochemical and paleoenvironmental changes during the T-OAE. Therefore, a new model of formation for the Early Jurassic carbonate fans is required.
- Publication:
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AGU Fall Meeting Abstracts
- Pub Date:
- December 2016
- Bibcode:
- 2016AGUFMPP13D..07M
- Keywords:
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- 1039 Alteration and weathering processes;
- GEOCHEMISTRYDE: 1050 Marine geochemistry;
- GEOCHEMISTRYDE: 4805 Biogeochemical cycles;
- processes;
- and modeling;
- OCEANOGRAPHY: BIOLOGICAL AND CHEMICALDE: 4924 Geochemical tracers;
- PALEOCEANOGRAPHY