The Science of Inaccurate Temperatures: Explaining How the Bahamas Did Not Form in a Jacuzzi

The Bahamas archipelago is a carbonate platform that formed in the warm waters of the Gulf Stream current. Using clumped isotope paleothermometry, it has been shown that carbonates extending back through the Miocene taken from cores throughout the Bahamas have all precipitated from fluids at temperatures similar to what is found in the Bahamas in the present day (15 to 35°C). However, in a single core, (Clino), collected off the western edge of Great Bahama Bank, Δ47 values have been measured which suggest formation at significantly warmer temperatures (42 to 53°C). These values are present in spite of the fact that the sediments have never been deeply buried. In a parallel study, these same cores were measured for their carbonate associated sulfate (CAS). The only core that presented evidence of elevated CAS, indicative of bacterial sulfate reduction (BSR), was the Clino core. In this core the clumped isotope temperatures are correlated with changes in the δ34S of the CAS. This finding suggests that BSR can have a significant effect on the Δ47 value producing erroneous temperatures. This is further supported by examining a carbonate concretion with extreme negative δ13C values (-30‰) taken as evidence of BSR. The clumped isotope temperatures in this nodule are elevated relative to its burial history with an increase of 15 °C from the outer edge of the concretion to the center. The increase in temperature correlates well with the decreasing δ13C suggesting increasing fractionation associated with BSR is directly impacting the clumped isotope measurements.