Effects of geothermal activity and primary production on molybdenum isotopes: Lake Mývatn, Iceland

Molybdenum (Mo) is highly sensitive to oxidation state and its isotopes are used as a proxy for redox conditions in the palaeoenvironent, particularly in the oceans. Geothermal systems play an important role in element cycles, comprising 10% of the Mo flux to the oceans and the dominant mechanism for Mo ore formation in porphyry deposits. Currently, little is known about Mo isotopes in either geothermal or groundwaters or how these systems may affect global mass balance. This study takes the Lake Mývatn area as a natural laboratory to study both geothermally affected and unaffected groundwaters, along with seasonal variations in a lacustrine environment. We present a comprehensive elemental and Mo isotope study of two groundwater systems from a basaltic terrain in North Iceland. The waters are of meteoric origin, range in sampling temperature from 2-93°C and in Mo isotope composition (δ98MoNIST) from -0.40 to 1.81‰. The Mo isotopic signature of the waters is largely controlled by mixing between cold groundwaters (isotopically light) and a geothermal end member (isotopically heavy). One of these groundwater systems forms the only input into Lake Mývatn: one of the most productive lakes in the northern hemisphere. Here we also present a time series from the Laxá River, which is the only outflow from the lake. Whilst seasonal variations in Mo isotopes are small (from δ98MoNIST 0.1 to 0.3‰) they positively correlate (R2 = 0.8) with variations in δ34S (from δ43S 1.7 to 4.6‰) with a shift to a heavier isotope peaks in late summer (September). This increase in δ98Mo coincides with a documented cyanobacteria bloom in late July to early September, known to preferentially use light isotopes.