Afloat in a Boat: Linking Land Use / Land Cover to the Spatial Evolution of Water Quality along a Blackwater Stream

Water quality and land use/land cover (LULC) are linked intimately in many watersheds, although exact relationships are often nonlinear and sometimes complex. Together with watershed topography, LULC can affect water quality in various ways. As such, attributing water quality characteristics to LULC variations (either in space or time) can be difficult. Many studies seek to understand these relationships from a Eulerian reference frame, which typically involves many samples or observations through time at a fixed location. Here we explore an alternative approach to understanding relationships between LULC and water quality that relies on a Lagrangian, or moving, reference frame, in which the effects of LULC and watershed topography on water quality can be observed through a different lens. We studied three reaches of the Lumber River, a blackwater stream in North Carolina's Coastal Plain, to assess relationships between LULC and water quality in a watershed that is a patchwork of agriculture, forests, wetlands and developed land. Our study combines spatially intensive water quality measurements (temperature, specific conductance, dissolved oxygen, pH and nitrate concentration), collected by boat, with geospatial analyses of LULC to understand influences on the spatial evolution of reach-scale water quality. In particular, we investigate relationships between spatial patterns in nitrate and the changing spatial characteristics of the watershed integrated at sampling points along each reach. We also assess relationships between nitrate and other water quality variables, such as pH, temperature, and dissolved oxygen to better understand the potential role of in-stream nutrient processing in observed spatial patterns. This work has implications for the regulation and management of agriculture, wetlands, and forests in a region that has long struggled to balance agriculture, a major economic driver, with water quality, a major concern for recreation and cultural practices locally and for nutrient sensitive coastal environments downstream.