Are the Laurentian Great Lakes a CO2 Source or Sink?

As concentrations of CO2 increase in our atmosphere, large bodies of water are prone to an accompanying increase in CO2. Accruing CO2 sinking into the Great Lakes can create more acidic waters, which is detrimental to the healthy growth of organisms producing calcium carbonate skeletons - a phenomenon that has been confirmed in modern oceans. Recent estimates suggests that Lake Huron, Lake Michigan, and Lake Superior are sources of atmospheric CO2, while Lake Erie and Lake Ontario are CO2 sinks, although this is based largely on water volume and little research has been done to validate these predictions. Water samples were collected aboard the University National Oceanographic Laboratory System RV Blue Heron and the Canadian Coast Guard RV Limnos from Lake Superior, Lake Michigan, and Lake Erie during the summer of 2016. Alkalinity and pCO2 were analyzed in lab to further calculate dissolved concentrations and fluxes of CO2, providing more information to resolve whether the Great Lakes are a CO2 source or sink. Additional work involves sampling all five of the Great lakes throughout the year to determine any seasonal trends in CO2. 13C-DIC will also be measured in order to differentiate methane oxidation and respiration to the CO2 pool.