Correlated cosmogenic W and Os isotopic variations in Carbo and implications for Hf-W chronology
Abstract
An obstacle for establishing the chronology of iron meteorite formation using 182Hf-182W systematics (t1/2 = 8.9 Myr) is to find proper neutron fluence monitors to correct for cosmic ray modification of W isotopic composition. Recent studies showed that siderophile elements such as Pt and Os could serve such a purpose. To test and calibrate these neutron dosimeters, the isotopic compositions of W and Os were measured in a slab of the IID iron meteorite Carbo. This slab has a well-characterized noble gas depth profile reflecting different degrees of shielding to cosmic rays. The results show that W and Os isotopic ratios correlate with distance from the pre-atmospheric center. Negative correlations, barely resolved within error, were found between ɛ190Os-ɛ189Os and ɛ186Os-ɛ189Os with slopes of -0.64 ± 0.45 and -1.8(+1.9/-2.1), respectively. These Os isotope correlations broadly agree with model predictions for capture of secondary neutrons produced by cosmic ray irradiation and results reported previously for other groups of iron meteorites. Correlations were also found between ɛ182W-ɛ189Os (slope = 1.02 ± 0.37) and ɛ182W-ɛ190Os (slope = -1.38 ± 0.58). Intercepts of these two correlations yield pre-exposure ɛ182W values of -3.32 ± 0.51 and -3.62 ± 0.23, respectively (weighted average ɛ182W = -3.57 ± 0.21). This value relies on a large extrapolation leading to a large uncertainty but gives a metal-silicate segregation age of -0.5 ± 2.4 Myr after formation of the solar system. Combining the iron meteorite measurements with simulations of cosmogenic effects in iron meteorites, equations are presented to calculate and correct for cosmogenic effects on 182W using Os isotopes.
- Publication:
-
Geochimica et Cosmochimica Acta
- Pub Date:
- March 2015
- DOI:
- 10.1016/j.gca.2014.11.015
- Bibcode:
- 2015GeCoA.153...91Q