Structural, optical and electrochromic properties of RF magnetron sputtered WO3 thin films

Thin films of tungsten trioxide (WO₃) have been prepared by RF reactive magnetron sputtering of tungsten target at different substrate temperatures in the range 303-673 K and at fixed oxygen partial pressure of 6×10^-2 Pa and sputter pressure of 4 Pa. The effect of substrate temperature on the structural, morphological, optical and electrochromic properties of WO₃ films was systematically studied. The films formed at 303 K were of X-ray amorphous, while those deposited at substrate temperatures ≥473 K were crystallized into orthorhombic phase WO₃. The crystallite size of the films increased from 17 to 24 nm with increase of substrate temperature from 473 to 673 K. Raman studies confirmed that the presence of O-W-O and W=O bonds in WO₃ films. The surface morphology of the films was significantly varied with substrate temperature. The optical transmittance data revealed that the optical band gap increased from 3.08 to 3.48 eV and refractive index increased from 2.18 to 2.26 with increase of substrate temperature from 303 to 673 K respectively. The WO₃ films formed at substrate temperature of 473 K exhibited better optical transmittance modulation of 40% between colored and bleached state with a color efficiency of 33.8 cm²/C and diffusion coefficient of 1.85×10^-11 cm²/s.