Fluctuations of Intensive Quantities in Statistical Thermodynamics
Abstract
In phenomenological thermodynamics, the canonical coordinates of a physical system split in pairs, with each pair consisting of an extensive quantity and an intensive one. In the present paper, the quasithermodynamic fluctuation theory of a model system of a large number of oscillators is extended to statistical thermodynamics based on the idea of perceiving the fluctuations of intensive variables as the fluctuations of specific extensive ones in a "thermodynamically dual" system. The extension is motivated by the symmetry of the problem in the context of an analogy with quantum mechanics, which is stated in terms of a generalized Pauli problem for the thermodynamic fluctuations. The doubled Boltzmann constant divided by the number of particles plays a similar role as the Planck constant.
- Publication:
-
Entropy
- Pub Date:
- November 2013
- DOI:
- 10.3390/e15114889FILE: /proj/ads/abstracts/
- arXiv:
- arXiv:1309.4439
- Bibcode:
- 2013Entrp..15.4889R
- Keywords:
-
- fluctuations;
- thermodynamics;
- quantization;
- Pauli problem;
- duality;
- Mathematical Physics
- E-Print:
- 24 pages