Low temperature growth of ultra-high mass density carbon nanotube forests on conductive supports
Abstract
We grow ultra-high mass density carbon nanotube forests at 450 °C on Ti-coated Cu supports using Co-Mo co-catalyst. X-ray photoelectron spectroscopy shows Mo strongly interacts with Ti and Co, suppressing both aggregation and lifting off of Co particles and, thus, promoting the root growth mechanism. The forests average a height of 0.38 μm and a mass density of 1.6 g cm-3. This mass density is the highest reported so far, even at higher temperatures or on insulators. The forests and Cu supports show ohmic conductivity (lowest resistance ∼22 kΩ), suggesting Co-Mo is useful for applications requiring forest growth on conductors.
- Publication:
-
Applied Physics Letters
- Pub Date:
- August 2013
- DOI:
- Bibcode:
- 2013ApPhL.103g3116S
- Keywords:
-
- aggregation;
- carbon nanotubes;
- catalysts;
- electric resistance;
- electrical conductivity;
- nanofabrication;
- X-ray photoelectron spectra;
- 81.07.De;
- 82.65.+r;
- 82.80.Pv;
- 61.48.De;
- 73.63.Fg;
- Nanotubes;
- Surface and interface chemistry;
- heterogeneous catalysis at surfaces;
- Electron spectroscopy;
- Structure of carbon nanotubes boron nanotubes and closely related graphitelike systems;
- Nanotubes