Neodymium and carbon isotopic fingerprints of warm Pliocene circulation throughout the deep Atlantic

The mid-Piacenzian age of the Pliocene is the most recent interval in Earth's history to sustain global warmth within the range predicted for the 21st century. To understand this interval, the USGS PRISM Project has developed a reconstruction of global conditions at 3.264-3.025 Ma, which includes a significant North Atlantic warm SST anomaly coupled with increased evaporation. Warm anomalies are also detected in the deep ocean as far as 46°S, suggesting that enhanced meridional overturning circulation may have been responsible for more southerly penetration of North Atlantic Deep Water (NADW). However, deep temperature proxies are not diagnostic of water mass, and some coupled model simulations predict transient decreases in NADW production in the 21st century, presenting a contrasting picture of future climate. We present a new multi-proxy synthesis of Atlantic deep ocean circulation during the PRISM interval, using the neodymium isotopic composition (ɛ_Nd) of fossil fish teeth as a proxy for water mass source and the δ¹³C of benthic foraminifera as a proxy for water mass age. This reconstruction utilizes both new and previously published data from 11 DSDP and ODP sites in the North Atlantic (Site 610) and along depth transects from equatorial Ceara Rise, southern mid-latitude Walvis Ridge, and south Atlantic Meteor Rise/Agulhas Ridge. Published data from ferromanganese crusts constrain Pliocene Antarctic deep waters at ~ ɛ_Nd = -8, distinct from the less radiogenic ɛ_Nd = -11.5 that characterizes Pliocene northern component water (NCW). These values fingerprint northern and southern sources throughout the Atlantic basin. Pliocene fish teeth from Site 610 (2400 m water depth) and from four Ceara Rise sites (3000-4300 m) preserve distinctly North Atlantic ɛ_Nd. When averaged across the PRISM interval, mean values for these five sites range from ɛ_Nd = -10.97 to -10.25, and the Pliocene depth transect closely mirrors the structure of the modern column, indicating that Ceara Rise was dominantly influenced by NCW at all depths. In contrast, Walvis Ridge water column structure was significantly different in the Pliocene. Today, a core of NADW between 1800 and 3500 m overlies abyssal southern component water (SCW). During the Pliocene, however, sites at 4000 and 4700 m were influenced exclusively by NCW, with PRISM mean ɛ_Nd of -11.14 and -11.45. In contrast, mean ɛ_Nd = -9.86 indicates that the shallowest site (2500 m), which sits in the core of NADW today, was instead influenced by SCW throughout the PRISM interval. The Meteor Rise/Agulhas Ridge transect provides further evidence for south Atlantic restructuring in the warm Pliocene. At the deepest Agulhas Ridge site (3700 m), PRISM mean ɛ_Nd = -8.47, an unequivocally SCW signature. Today, the shallower Meteor Rise sites (2000 and 2500 m) are within NADW, yet mean PRISM ɛ_Nd = -7.68 and -7.82 - more radiogenic than the SCW end member - raising the possibility that south Atlantic intermediate waters incorporated both Pacific and Antarctic components in the Pliocene.