Carbon and Neodymium Isotopic Fingerprints of Atlantic Deep Ocean Circulation During the Warm Pliocene

Earth's future climate may resemble the mid-Piacenzian Age of the Pliocene, a time when global temperatures were sustained within the range predicted for the coming century. Surface and deep water temperature reconstructions and coupled ocean-atmosphere general circulation model simulations by the USGS PRISM (Pliocene Research Interpretation and Synoptic Mapping) Group identify a dramatic North Atlantic warm surface temperature anomaly in the mid-Piacenzian (3.264 - 3.025 Ma), accompanied by increased evaporation. The anomaly is detected in deep waters at 46°S, suggesting enhanced meridional overturning circulation and more southerly penetration of North Atlantic Deep Water (NADW) during the PRISM interval. However deep water temperature proxies are not diagnostic of water mass and some coupled model simulations predict transient decreases in NADW production in the 21st century, presenting a contrasting picture of future climate. We present a new multi-proxy investigation of Atlantic deep ocean circulation during the warm mid-Piacenzian, using δ¹³C of benthic foraminifera as a proxy for water mass age and the neodymium isotopic composition of fossil fish teeth (ɛ_Nd) as a proxy for water mass source and mixing. This reconstruction utilizes both new and previously published data from DSDP and ODP cores along equatorial (Ceara Rise), southern mid-latitude (Walvis Ridge), and south Atlantic (Meteor Rise/Agulhas Ridge) depth transects. Additional end-member sites in the regions of modern north Atlantic and Southern Ocean deep water formation provide a Pliocene baseline for comparison. δ¹³C throughout the Atlantic basin is remarkably homogenous during the PRISM interval. δ¹³C values of Cibicidoides spp. and C. wuellerstorfi largely range between 0‰ and 1‰ at North Atlantic, shallow equatorial, southern mid-latitude, and south Atlantic sites with water depths from 2000-4700 m; both depth and latitudinal gradients are generally small (~0.3‰). However, equatorial Ceara Rise sites below 3500 m diverge, with δ¹³C values as low as -1.2‰ at ~3.15 Ma. The uniquely negative δ¹³C values at deep Ceara rise sites suggest that, during PRISM warmth, the oldest Atlantic deep waters may have resided along the modern deep western boundary current, while younger deep water masses were concentrated to the south and east. In the modern Atlantic, the ɛ_Nd value of southern-sourced waters is more radiogenic than that of northern-sourced waters, providing a complimentary means to characterize Pliocene water mass geometry. ɛNd values from shallow (2500 m) and deep (4700 m) Walvis Ridge sites average -10 and -11 respectively; the shallow site is somewhat more radiogenic than published coretop ɛ_Nd (-12), suggesting enhanced Pliocene influence of southern-sourced water masses. Ongoing analytical efforts will fingerprint Piacenzian ɛ_Nd from north and south deep water source regions and will target additional depth transect ɛ_Nd, allowing us to investigate the possibility that "older" carbon isotopic signatures at western equatorial sites reflect entrainment of proto-NADW while "younger" signatures at southern and eastern sites reflect the influence of southern-sourced deep water.