Co-seismic thermal dissociation of carbonate fault rocks: Naukluft Thrust, central Namibia

Frictional heating has been shown to dissociate carbonate minerals in fault rocks and rock slides at high velocities, producing in-situ fluid pressure spikes and resulting in very low effective friction. We describe the textural and geochemical effects of repeated events of frictional-thermal dissociation and fluidization along a low-angle continental thrust fault. The Naukluft Thrust in central Namibia is a regional décollement along which the Naukluft Nappe Complex was emplaced over the Nama Basin in the southern foreland of the ~ 550Ma Damara Orogen. Fault rocks in the thrust show a coupled geochemical and structural evolution driven by dolomitization reactions during fault activity and facilitated by fluid flow along the fault surface. The earliest developed fault rocks are calcite-rich calcmylonites which were progressively dolomitized along foliation. Above a critical dolomite/calcite ratio, the rocks show only brittle deformation fabrics dominated by breccias, cataclasites, and locally, a thin (1-3cm) microcrystalline, smooth white ultracataclasite. The fault is characterized by the prevalence of an unusual “gritty dolomite” yellow cataclasite containing very well rounded clasts in massive to flow-banded fine dolomitic matrix. This cataclasite, locally known as the “gritty dolomite”, may reach thicknesses of up to ~ 10m without evidence of internal cross-cutting relations with randomly distributed clasts (an “unsorted” texture). The gritty dolomite also forms clastic injections into the hanging wall of the fault, frequently where the fault surface changes orientation. Color-cathodoluminescence images show that individual carbonate grains within the “gritty dolomite” have multiple layers of thin (~10-100 micron) dolomite coatings and that the grains were smoothed and rounded between each episode of coating precipitation. Coated grains are in contact with one another but grain cores are never seen in contact. CL-bright red dolomite which forms the coatings is never observed as pore-fill between grains or other geometries typical of cement precipitates. Smoothness and radial symmetry of the coatings suggest that the grains were coated in suspension by very fine material, potentially analogous to the frictionally-generated CaO developed on the base of some landslides in carbonate rocks (Hewitt, 1988). The very thick layers of cataclasite without internal crosscutting suggest free particle paths associated with fluidization at high fluid pressure and low effective normal stress. We suggest that co-seismic frictional heating along the Naukluft Thrust caused dissociation of dolomite fault rock, producing in-situ spikes in fluid pressure (CO2) and very fine caustic CaO which chemically attacked the carbonate grains in suspension causing the smoothing and rounding. These residues then coated individual grains prior to loss of fluid pressure and settling in the fault zone. Such an event would have been associated with near total strength drop along the Naukluft Thrust. Hewitt, K., 1988 Science, v. 242, no. 4875, p. 64-67.