Superconductivity at 43 K at ambient pressure in the iron-based layered compound La1-xYxFeAsOy
Abstract
Effect of Y substitution on the La-based iron oxypnictide superconductor LaFeAsO0.6 is studied. Replacement of La3+ (1.16Å) by smaller Y3+ (1.019Å) in a form of La1-xYxFeAsO0.6 results in the decrease in lattice parameters, which likely causes pressure effect into the system. Superconducting transition temperature (Tc) increases monotonically with x , eventually up to 43.1 K for x=0.5 . This Tc is comparable to the highest Tc reported for Y-free F-doped LaFeAsO1-xFx under high pressure. The present results provide an alternative and much simpler way to achieve higher Tc in the La-based oxypnictide superconductors.
- Publication:
-
Physical Review B
- Pub Date:
- November 2008
- DOI:
- Bibcode:
- 2008PhRvB..78q2503S
- Keywords:
-
- 74.25.Fy;
- 74.70.-b;
- 07.35.+k;
- 61.05.cp;
- Transport properties;
- Superconducting materials;
- High-pressure apparatus;
- shock tubes;
- diamond anvil cells;
- X-ray diffraction