The toroidal moment in condensed-matter physics and its relation to the magnetoelectric effect
Abstract
The concept of toroidal moments in condensed-matter physics and their long-range ordering in a so-called ferrotoroidic state is reviewed. We show that ferrotoroidicity as a form of primary ferroic order can be understood both from microscopic (multipole expansion) and macroscopic (symmetry-based expansion of the free energy) points of view. The definition of the local toroidal moment and its transformation properties under the space-inversion and time reversal operations are highlighted and the extension to periodic bulk systems is discussed. Particular attention is paid to the relationship between the toroidal moment and the antisymmetric magnetoelectric effect and to limitations of the magnetoelectric response in ferrotoroidic systems and ferroic materials in general. Experimental access to the ferrotoroidic state by magnetoelectric susceptibility measurements, x-ray diffraction and optical techniques or direct measurement of the bulk toroidization is discussed. We outline the pertinent questions that should be clarified for continued advancement of the field and mention some potential applications of ferrotoroidic materials.
All authors contributed equally to this work.- Publication:
-
Journal of Physics Condensed Matter
- Pub Date:
- October 2008
- DOI:
- 10.1088/0953-8984/20/43/434203
- Bibcode:
- 2008JPCM...20Q4203S