Rotational spectrum and equilibrium structure of silanethione, H2Si=S
Abstract
Unsubstituted silanethione, H2Si=S, has been characterized experimentally for the first time by means of rotational spectroscopy; the equilibrium structure of this fundamental molecule has been evaluated through a combination of experimental data from a total of ten isotopologues and results of high-level coupled-cluster calculations.
- Publication:
-
Chemical Communications
- Pub Date:
- November 2008
- Bibcode:
- 2008ChCom..44.5292T