Noblest of All Metals Is Structurally Unstable at High Pressure

In a series of experiments in externally electrically heated diamond anvil cells we demonstrate that at pressures above ∼240GPa gold adopts a hexagonal close-packed structure. Ab initio calculations predict that at pressures about 250 GPa different stacking sequences of close-packed atomic layers in gold become virtually degenerate in energy, strongly supporting the experimental observations.