Variable parent magmas and recharge regimes of the Parinacota magma system (N. Chile) revealed by Fe, Mg and Sr zoning in plagioclase

Zoning patterns of An content and Fe, Mg and Sr concentrations in plagioclase phenocrysts in andesites from Parinacota Volcano (N. Chile) reflect alternating recharge events with two chemically distinct mafic magmas. These magmas are characterized by low and high Sr contents, similar to two recent mafic flank eruptions. One end-member basaltic andesite shows large Sr enrichment and Heavy Rare Earth depletions and thus equilibrated with lower-crustal rocks at depth where plagioclase (high Sr) is unstable, and garnet (high HREE, Y) is stable. A second end-member magma is lower in Sr, Ba contents and has REE patterns typical for parent magmas elsewhere in the Central Andes. The number of recorded recharge events increases after a catastrophic sector collapse and during the subsequent rebuilding of the stratocone. Variations of An, Fe and Mg contents and morphology of zones suggest also changes in water pressure, including decompression under water under-saturated and water-saturated conditions. Evidence for decompression is more present in post-collapse samples, suggesting that the change in the volcano dynamics involves changes in magma chamber location. This shows the importance of the cone collapse event in the volcano's magmatic evolution. We propose that both end-members are only seen at the surface of Parinacota Volcano because of the particular dynamics of this volcanic system and that similar processes might occur in other volcanic centres of the Central Volcanic Zone.