Long-Term Controls on Solute and Sediment Fluxes From a Rapidly Weathering Tropical Watershed

The 326-ha Rio Icacos watershed in the tropical wet forest of the Luquillo Mountains, northeastern Puerto Rico, is underlain by granodiorite bedrock with weathering rates among the highest in the world. We pooled stream chemistry and suspended sediment datasets from three discrete periods: 1983-87; 1991-97; and 2000-05, which bracket two major hurricanes that crossed the site; Hugo in 1988 and Georges in 1998. This mountainous landscape is also subject to frequent disturbance by landslides. Stream major ion chemistry reflects weathering of the granodiorite, but dilutes by as much as 90% during the largest storms. This dilution reflects the increasing dominance of rainwater (and cloud water) with increasing streamflow, as major ion stoichiometry is maintained except when precipitation is high in sea salt. Given the broad area of surface saturation, low-permeability soils, and flashy stream hydrograph which quickly returns to base flow, it appears that precipitation moves to the stream by saturation overland flow. Piping and rapid shallow subsurface flow through the rooting zone may also facilitate precipitation movement off hillslopes. Concentration-discharge relations for most major ions were fairly stable through time, suggesting minimal long-term effects from disturbance. The exception was nitrate, which increased from near 5 μmol L-1 during the 1983-87 period to greater than 12 μmol L-1 and remaining elevated for several years following each of the two hurricanes. The relation between suspended sediment concentration and discharge was also stable over time but exhibited more variability, some due to hysteresis but some likely caused by pulsed sediment from discrete disturbances.