Entropy Production along a Stochastic Trajectory and an Integral Fluctuation Theorem
Abstract
For stochastic nonequilibrium dynamics like a Langevin equation for a colloidal particle or a master equation for discrete states, entropy production along a single trajectory is studied. It involves both genuine particle entropy and entropy production in the surrounding medium. The integrated sum of both Δstot is shown to obey a fluctuation theorem <exp([-Δstot]>=1 for arbitrary initial conditions and arbitrary time-dependent driving over a finite time interval.
- Publication:
-
Physical Review Letters
- Pub Date:
- July 2005
- DOI:
- 10.1103/PhysRevLett.95.040602
- arXiv:
- arXiv:cond-mat/0503686
- Bibcode:
- 2005PhRvL..95d0602S
- Keywords:
-
- 05.40.-a;
- 05.70.-a;
- Fluctuation phenomena random processes noise and Brownian motion;
- Thermodynamics;
- Condensed Matter - Statistical Mechanics;
- Condensed Matter - Soft Condensed Matter
- E-Print:
- 4 pages, RevTex