Microscopic Models for Chemical Thermodynamics
Abstract
We introduce an infinite particle system dynamics, which includes stochastic chemical kinetics models, the classical Kac model and free space movement. We study energy redistribution between two energy types (kinetic and chemical) in different time scales, similar to energy redistribution in the living cell. One example is considered in great detail, where the model provides main formulas of chemical thermodynamics.
 Publication:

Journal of Statistical Physics
 Pub Date:
 June 2005
 DOI:
 10.1007/s109550054408z
 arXiv:
 arXiv:1112.1769
 Bibcode:
 2005JSP...119..997M
 Keywords:

 Chemical thermodynamics;
 infinite particle systems;
 Kac model;
 chemical kinetics;
 Mathematical Physics;
 Condensed Matter  Statistical Mechanics;
 82C03
 EPrint:
 Journal of Statistical Physics, 2005, v. 119, No. 5/6, pp. 9971026