Microscopic Models for Chemical Thermodynamics
Abstract
We introduce an infinite particle system dynamics, which includes stochastic chemical kinetics models, the classical Kac model and free space movement. We study energy redistribution between two energy types (kinetic and chemical) in different time scales, similar to energy redistribution in the living cell. One example is considered in great detail, where the model provides main formulas of chemical thermodynamics.
- Publication:
-
Journal of Statistical Physics
- Pub Date:
- June 2005
- DOI:
- 10.1007/s10955-005-4408-z
- arXiv:
- arXiv:1112.1769
- Bibcode:
- 2005JSP...119..997M
- Keywords:
-
- Chemical thermodynamics;
- infinite particle systems;
- Kac model;
- chemical kinetics;
- Mathematical Physics;
- Condensed Matter - Statistical Mechanics;
- 82C03
- E-Print:
- Journal of Statistical Physics, 2005, v. 119, No. 5/6, pp. 997-1026