Cation-cation interaction in crystalline actinide compounds
Abstract
The published data on the structures and properties of crystalline actinide compounds having mutually coordinated AnO2+ or AnO22+ cations as structural elements are surveyed. This cation-cation interaction is an important structure-forming factor for many crystalline compounds of Np(V) and U(VI). It strongly affects their UV-Vis and IR spectra as well as other properties. Differences and similarities between the cation-cation interactions of actinide ions in solutions and crystals are discussed.
- Publication:
-
Russian Chemical Reviews
- Pub Date:
- January 2004
- DOI:
- 10.1070/RC2004v073n01ABEH000852
- Bibcode:
- 2004RuCRv..73...89K