Kohn Anomalies and Electron-Phonon Interactions in Graphite
Abstract
We demonstrate that graphite phonon dispersions have two Kohn anomalies at the Γ-E2g and K-A'1 modes. The anomalies are revealed by two sharp kinks. By an exact analytic derivation, we show that the slope of these kinks is proportional to the square of the electron-phonon coupling (EPC). Thus, we can directly measure the EPC from the experimental dispersions. The Γ-E2g and K-A'1 EPCs are particularly large, while they are negligible for all the other modes at Γ and K.
- Publication:
-
Physical Review Letters
- Pub Date:
- October 2004
- DOI:
- 10.1103/PhysRevLett.93.185503
- arXiv:
- arXiv:cond-mat/0407164
- Bibcode:
- 2004PhRvL..93r5503P
- Keywords:
-
- 63.20.Dj;
- 63.20.Kr;
- 71.15.Mb;
- 78.30.-j;
- Phonon states and bands normal modes and phonon dispersion;
- Phonon-electron and phonon-phonon interactions;
- Density functional theory local density approximation gradient and other corrections;
- Infrared and Raman spectra;
- Condensed Matter - Materials Science
- E-Print:
- 4 pages, 2 figures