Synthesis, structural characterization and ferrimagnetic property of MnPS 3 intercalated with nickel(II) cyclopolyamine complex cations
Abstract
Two new intercalation compounds were prepared by the reactions of Ni(II) cyclopolyamine complex cations with a preintercalate Mn 1-xPS 3K 2x(H 2O) y, respectively, through "ion exchange" process. Their structures were characterized by elemental analysis, X-ray powder diffraction and infrared spectroscopy. The lattice spacing increased 0.567 and 1.093 nm with respect to the pristine MnPS 3. Ferrimagnetism of the intercalates was confirmed by SQUID experiment with Tc at 40 and 33 K, respectively.
- Publication:
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Journal of Solid State Chemistry France
- Pub Date:
- November 2004
- DOI:
- Bibcode:
- 2004JSSCh.177.4300Y