Intra-Volcano Compositional Variability and the Role of Oceanic Lithosphere in West Maui and East Molokai Volcanoes
Abstract
West Maui and East Molokai, two Hawaiian volcanoes with depleted, Kea-type isotopic compositions, show fine-scale, intra-volcano isotopic correlations in the shield-stage lavas that are distinct from inter-volcano correlations across the Hawaiian chain. Strong isotopic similarities exist in stratigraphic sections through the late shield stage of these two contemporaneous (1.5-2 Ma) Kea-type volcanoes. The depleted Hf, Pb, Sr and Nd isotope compositions of W. Maui and E. Molokai show limited variability and have a strong affinity to the Hawaiian Kea component. ɛHf ranges from +11.5 to +13.5 and +12.6 to +13.3 in W. Maui and E. Molokai, respectively; W. Maui shows an increase in ɛHf with depth. 206Pb/204Pb compositions are 18.34-18.54 and 18.42-18.59 for these same volcanoes. Hf and Pb isotope compositions do not correlate significantly. Even over a limited isotopic range, ɛNd compositions (W. Maui: +6.6 to +7.6; E. Molokai: +7.1 to +7.3) correlate inversely with 87Sr/86Sr (W. Maui: 0.70337-0.70363; E. Molokai: 0.70341-0.70362). 87Sr/86Sr and 206Pb/204Pb compositions in E. Molokai and deeper samples from W. Maui show a positive, linear correlation. This trend is orthogonal to the inter-volcano Hawaiian trend, and thus does not reflect mixing between components that typically dominate archipelago-scale sampling of magma sources in Hawaii. A positive Sr-Pb isotope correlation may reflect involvement of oceanic lithosphere, the geochemical signature of which is age-dependent. We have modeled the isotopic compositions of upper, hydrothermally altered basaltic segments and lower gabbroic segments of ancient (1.5-2 Ga) and younger (110 Ma) oceanic lithosphere. The fine-scale compositional trends we observe at W. Maui and E. Molokai are consistent with the interaction of plume-generated Kea-type magmas with the local, 110 Ma Pacific lithosphere. These compositional variations are observed only in specific sections of the stratigraphy, and so must result from processes that operate over time scales much shorter than the life of the volcano.
- Publication:
-
AGU Fall Meeting Abstracts
- Pub Date:
- December 2002
- Bibcode:
- 2002AGUFM.V62B1399G
- Keywords:
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- 1000 GEOCHEMISTRY (New field;
- replaces Rock Chemistry);
- 1010 Chemical evolution;
- 1040 Isotopic composition/chemistry;
- 1065 Trace elements (3670)