Giant dielectric constant response in a copper-titanate
Abstract
We describe a material, cubic CaCu 3Ti 4O 12, which exhibits a large dielectric response, the temperature-dependence of which has not been seen, to our knowledge, in any existing material. This compound possesses a low-frequency dielectric constant, ɛ∼10 4[1], which is only weakly varying in the temperature range 100-400 K. Below T∼100 K, however, there is an abrupt 100-fold reduction in the value of ɛ. X-ray diffraction and thermodynamic data argue against an explanation in terms of ferroelectricity, i.e. the collective ordering of local dipole moments. Both the low-frequency dielectric response as well as Raman scattering data suggest the existence of highly polarizable relaxational modes with a characteristic gap energy of 28 meV.
- Publication:
-
Solid State Communications
- Pub Date:
- June 2000
- DOI:
- 10.1016/S0038-1098(00)00182-4
- Bibcode:
- 2000SSCom.115..217R